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Surface Modification of Hydroxyapatite by Using γ-aminopropyl Silane
作者姓名:张胜民
作者单位:ZHANG Sheng-min LI Shi-pu YAN Yu-hua WAN Tao JIANG Xin HAN Chang-ri SONG Xiao-ping1) Wuhan University of Technology,2) Hainan Normal University
基金项目:This work was supported by Hubei Natural Science Founda-tion (NO.99J055) and the Key Project of the Ministry of Science and Technology (NO. 96-920-20-11)
摘    要:Surface modification of hydroxyapatite( HA) powder was performed with r-aminopropyi silane in toluent solvent. The modification effects were characterized by using XPS and FT-IR methods . The results indicated that the P2p electron binding energy of the modified HA decreases 0.4 eV compared to that of HA . Furthermore , a new peak, 998cm-1 absorption appeared in IR differential spectra of modified HA and HA, which is due to a stretching vibration of structure P-O-Si, meaning that a direct covalent bonding between hydroxyl group on HA surface and the organic silane molecule was realized after modification, and the chemical bonding type was P- O-Si. The formation of the above structure suggested that the more effective interfacial adhesion between the modified HA and polymer matrix could be carried out.

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