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Synthesis and electrochemiluminescence of the CeO2/TiO2 composite
Authors:Yi Zhu  Gai Li  Shengyi Zhang  Jiming Song  Changjie Mao  Helin Niu  Baokang Jin  Yupeng Tian
Affiliation:Department of Chemistry, Key Laboratory of Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230039, China
Abstract:CeO2/TiO2 composite with kernel–shell structure was synthesized by a sol–gel process. The characterization results show that the composite is made up of anatase phase TiO2 and cubic system CeO2. The electrochemiluminescence (ECL) behavior of the CeO2/TiO2 composite was studied by a cyclic voltammetry in the presence of persulfate, and the effect factors on ECL emission were discussed. Based on a series of experiments, it is proposed that the strong dual ECL emission produced by the CeO2/TiO2 composite resulted from the benefit ECL effect of interface heterojunction in composite.
Keywords:CeO2/TiO2 composite  Synthesis  Electrochemiluminescence
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