Effect of various sono-oxidation parameters on the desulfurization of diesel oil |
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Authors: | Yongchuan Dai Yutai Qi Dezbi Zhao |
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Affiliation: | (1) Key Laboratory of Microbial Metabolism, Ministry of Education, School of Life Sciences and Biotechnology, Shanghai Jiao Tong University, Shanghai, 200240, People’s Republic of China;(2) State Key Laboratory of Microbial Technology, Shandong University, Jinan, 250100, People’s Republic of China;(3) State Key Laboratory of Microbial Technology, Shandong University, Jinan, 250100, People’s Republic of China;(4) Institute of Microbiology, Chinese Academy of Sciences, Beijing, 100080, People’s Republic of China |
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Abstract: | The influences of ultrasonic intensity, H2O2 concentration, ratio of H2O2 to oil and the addition of Fenton reagent on the oxidative desulfurization of diesel oil under ultrasonic irradiation were
investigated. It was observed that the oxidative desulfurization of diesel oil fitted pseudo-first-order kinetics under our
experimental conditions. Increasing the ultrasonic intensity increased the oxidative desulfurization efficiency of diesel
oil. The addition of H2O2 enhanced the ultrasonic oxidative desulfurization efficiency of diesel oil. The sono-oxidation treatment in combination with
Fenton reagent showed a synergistic effect for diesel oil desulfurization. The catalytic oxidative desulfurization process
under ultrasonic irradiation process on diesel oils is an efficient and promising method. |
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