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Parametric study for the growth of carbon nanotubes by catalytic chemical vapor deposition in a fluidized bed reactor
Authors:Dario VenegoniPhilippe Serp  Roselyne FeurerYolande Kihn  Constantin VahlasPhilippe Kalck
Affiliation:a Laboratoire de Catalyse, Chimie Fine et Polymères-Ecole Nationale Supérieure d’Ingénieurs en Arts Chimiques et Technologiques, 118 Route de Narbonne, 31077 Toulouse Cédex 4, France
b Centre Interuniversitaire de Recherche et d’Ingénierie des Matériaux, UMR CNRS/INPT/UPS-Ecole Nationale Supérieure d’Ingénieurs en Arts Chimiques et Technologiques, 118 Route de Narbonne, 31077 Toulouse Cédex 4, France
c CEMES-CNRS no. 8011, 2 rue Jeanne Marvig, 31055 Toulouse, France
Abstract:Multiwalled carbon nanotubes have been produced from H2-C2H4 mixtures on Fe-SiO2 catalysts by a fluidized bed catalytic chemical vapor deposition process. Various parameters such as the catalyst preparation, the residence time, the run duration, the temperature, the H2:C2H4 ratio, the amount of metal deposited on the support have been examined. The influence of these parameters on the deposited carbon yield is reported, together with observations of the produced material. This process allows an homogeneously distributed deposition of nanotubes (10-20 nm diameter), that remain anchored to the support.
Keywords:A. Carbon nanotubes   Catalytically grown carbon   Vapor-grown carbon   B. Chemical vapor deposition   Catalyst
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