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Enhanced mass transfer at the rotating cylinder electrode. II. Development of roughness for solutions of decreasing concentration
Authors:D. R. Gabe  F. C. Walsh
Affiliation:(1) Department of Materials Engineering and Design, University of Technology, LE11 3TU Loughborough, Leicestershire, UK;(2) Present address: Wolfson Centre for Electrochemical Science, Department of Chemistry, University of Southampton, SO9 5NH Southampton, UK
Abstract:The development of roughness at a rotating cylinder electrode has been investigated in the context of a metal recovery system — the ECO-CELL — where the solution concentration necessarily falls with time under batch processing. Roughness has been quantified using knurled cylinders and the use of thiourea as an additive has been considered. The development of a rough surface allows a reactor to recover metal at enhanced rates and the exploitation of this feature is discussed.
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