| 介孔二氧化硅/Nafion复合材料的制备及其酸催化性能的研究 |
| |
| 引用本文： | 郑净植,胡建.介孔二氧化硅/Nafion复合材料的制备及其酸催化性能的研究[J].湖北化工,2012(6):59-61. |
| |
| 作者姓名： | 郑净植 胡建 |
| |
| 作者单位： | 武汉工程大学化工与制药学院绿色化工过程教育部重点实验室,湖北武汉430073 |
| |
| 基金项目： | 武汉工程大学科学研究基金资助项目（10115033） |
| |
| 摘 要： | 以十六烷基三甲基溴化铵为模板剂,正硅酸四乙酯和Nafion在碱性条件下共缩合制备介孔二氧化硅/Na-fion复合材料,利用傅立叶红外光谱（FTIR）、热失重分析（TGA）、氮气吸附脱附等手段对复合材料进行了表征,并对其酸催化性能进行了研究。结果表明,复合材料具有较好的孔道有序结构,Nafion树脂被引入到介孔二氧化硅骨架中;作为固体酸催化剂,对苯甲醛和乙二醇的加成反应表现出了较高的酸催化性能。
|
| 关 键 词： | 介孔二氧化硅 Nafion 复合材料 酸催化性能 |
Preparation of Mesoporous Silica/Nafion Composite and Study on Its Acid-Catalytic Performance |
| |
| ZHENG Jing-zhi,HU Jian.Preparation of Mesoporous Silica/Nafion Composite and Study on Its Acid-Catalytic Performance[J].Hubei Chemical Industry,2012(6):59-61. |
| |
| Authors: | ZHENG Jing-zhi HU Jian |
| |
| Affiliation: | (Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemical Engineering ＆ Pharmacy ,Wuhan Institute of Technology,Wuhan 430073,China) |
| |
| Abstract: | The mesoporous silica/Nafion composite was synthesized by co-condensation of Nafion solution and tetraethoxysilane using hexadecyltrimethylammonium bromide as template in alkaline aqueous solution. The composite was characterized by FTIR, TGA and Nz adsorption-desorption. The acid-catalytic performance of composite was studied also. The results indicated that the meso-structure of the composite was retained,and the Nation had been successfully incorporated into the skeleton of silica. The composite showed high acid-catalytic performance toward the addition reaction of benzaldehyde and ethylene glycol. |
| |
| Keywords: | mesoporous silica Nation composite acid-catalytic performance |
| 本文献已被 维普 等数据库收录！ |
