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X-ray photoelectron spectra of magnetite nanopowders after chromium(VI) sorption from aqueous solutions
Authors:M V Kuznetsov  O D Linnikov  I V Rodina
Affiliation:1.Institute of Solid State Chemistry, Ural Branch,Russian Academy of Sciences,Yekaterinburg,Russia
Abstract:Fe3O4 nanopowders prepared by three different procedures (vapor-phase synthesis, chemical precipitation from aqueous solutions, and laser evaporation) have been characterized by X-ray photoelectron spectroscopy before and after chromium(VI) sorption from aqueous solutions. The results demonstrate that, during sorption, the chromium is concentrated in the magnetite at a level of several atomic percent, and its oxidation state is 3+. The mechanism of chromium sorption on magnetite particles is discussed.
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