| Si4+和F-掺杂对LiNi1/3Co1/3Mn1/3O2结构和电化学性能的影响 |
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| 引用本文： | 张培新,张利,谭智博,任祥忠.Si4+和F-掺杂对LiNi1/3Co1/3Mn1/3O2结构和电化学性能的影响[J].中国有色金属学报,2011(11):2805-2811. |
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| 作者姓名： | 张培新 张利 谭智博 任祥忠 |
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| 作者单位： | 深圳大学化学与化工学院; |
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| 基金项目： | 国家自然科学基金资助项目(50874074); 广东省高等学校自然科学研究重点项目(05Z018) |
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| 摘 要： | 以Li2CO3、NiO、Co2O3、MnO2、LiF和SiO2为原料,采用机械力活化固相法制备了Si4+和F-掺杂的锂离子电池正极材料LiNi1/3Co 1/3Mn1/3O2.通过X射线衍射(XRD)、扫描电镜(SEM)和电化学性能测试等技术研究了LiNi1/3Co1/3Mn1/3O2的结构特征、形貌及电化学性能等.结...
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| 关 键 词： | LiNi1/3Co1/3Mn1/3O2 机械力活化 掺杂 电化学性能 |
Effect of Si~(4+) and F-~ doping on structure and electrochemical properties of LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2 |
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| ZHANG Pei-xin,ZHANG Li,TAN Zhi-bo,REN Xiang-zhong.Effect of Si~(4+) and F-~ doping on structure and electrochemical properties of LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2[J].The Chinese Journal of Nonferrous Metals,2011(11):2805-2811. |
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| Authors: | ZHANG Pei-xin ZHANG Li TAN Zhi-bo REN Xiang-zhong |
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| Affiliation: | ZHANG Pei-xin,ZHANG Li,TAN Zhi-bo,REN Xiang-zhong (School of Chemistry and Chemical Engineering,Shenzhen University,Shenzhen 518060,China) |
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| Abstract: | The layered LiNi1/3Co1/3Mn1/3O2 cathode materials doped by Si4+ and F- were synthesized by solid state of mechanical activation method using Li2CO3,NiO,Co2O3,MnO2,LiF and SiO2 as the raw materials.The bare sample and doping composites were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM) and charge-discharge test.The results show that doping does not change the crystal of materials,the doped samples have a smaller grain sizes and uniform distributions,furthermore,the composite Li(Ni... |
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| Keywords: | LiNi1/3Co1/3Mn1/3O2 mechanical activation doping electrochemical property |
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