Desorption of Cl- from Mg-Al layered double hydroxide intercalated with Cl- using CO2 gas and water |
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Authors: | Tomohito Kameda Hiroki Uchida Shogo Kumagai Yuko Saito Keiichi Mizushina Ichirou Itou Tianye Han Toshiaki Yoshioka |
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Affiliation: | 1.Graduate School of Environmental Studies, Tohoku University, 6-6-07 Aoba, Aramaki, Aoba-ku, Sendai 980-8579, Japan;2.Kurita Water Industries Ltd., Nakano Central Park East, 4-10-1 Nakano, Nakano-ku, Tokyo 164-0001, Japan |
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Abstract: | Mg-Al layered double hydroxide intercalated with CO32- (CO3·Mg-Al LDH) is effective for treating HCl exhaust gas. HCl reacts with CO32- in CO3·Mg-Al LDH, resulting in the formation of Cl·Mg-Al LDH. We propose that CO2 can be used for the desorption of Cl- from Cl·Mg-Al LDH to regenerate CO3·Mg-Al LDH. Herein, we studied the desorption of Cl- from Cl·Mg-Al LDH by adding water to Cl·Mg-Al LDH and blowing CO2 into it. We also analyzed the effects of temperature and water addition speed on the desorption of Cl- from Cl·Mg-Al LDH. Our results show that the added water adhered to Cl·Mg-Al LDH and that CO2 in the gaseous phase was dissolved in this adhered water, thus generating CO32-. Therefore, anion exchange occurred between CO32- and Cl- in the Cl·Mg-Al LDH, thus desorbing Cl-. |
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Keywords: | Mg-Al layered double hydroxide CO2 gas Cl-desorption Semi-dry method |
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