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Phase-modulated ellipsometry for probing the temperature-induced phase transition in ruthenium-doped lead zinc niobate-lead titanate single crystal
Authors:Chun-I ChuangVera Marinova  Shiuan-Huei LinYu-Faye Chao
Affiliation:
  • a Department of Photonics and Institute of Electro-Optical Engineering, National Chiao Tung University, 1001 University Rd., Hsinchu, Taiwan 300, ROC
  • b Central Laboratory of Optical Storage and Processing of Information, Bulgarian Academy of Sciences, P.O. Box 95, 1113 Sofia, Bulgaria
  • c Department of Electrophysics, National Chiao Tung University, 1001 University Rd., Hsinchu, Taiwan 300, ROC
  • Abstract:Phase-modulated ellipsometry was applied to measure changes in the refractive index of pure and ruthenium (Ru)-doped 0.9Pb (Zn1/3Nb2/3)O3 (PZN)-0.1PbTiO3 (PT) during the heating process in real time. Both samples were heated from room temperature to 200 °C in a thermally insulated chamber. In both samples, the phase transitions were observed to change from tetragonal to cubic. The temperature region at which the phase transition (Curie region) of Ru-doped 0.9PZN-0.1PT occurred not only broadened but also shifted to a lower temperature. The refractive indices were extremely stable in this region, meaning that Ru-doped 0.9PZN-0.1PT is a more favorable medium for the fabrication of optical memories.
    Keywords:Refractive index  Perovskite  Curie region  Ellipsometry
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