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球磨法制备POE-g-MAH/OMMT增韧母粒及其对PA6增韧改性
引用本文:王力,熊玉竹,罗金中. 球磨法制备POE-g-MAH/OMMT增韧母粒及其对PA6增韧改性[J]. 工程塑料应用, 2011, 39(9): 26-29
作者姓名:王力  熊玉竹  罗金中
作者单位:贵州大学材料与冶金工程学院,贵阳550003;国家复合改性聚合物材料工程技术研究中心,贵阳550014
基金项目:贵州大学引进人才科研项目;贵大人基合字2009(013号)
摘    要:通过球磨法制备马来酸酐接枝(乙烯-辛烯)共聚物(POE-g-MAH)/有机化蒙脱土(OMMT)增韧母粒,并将其用于尼龙(PA)6的增韧改性.结果表明,球磨法制备的POE-g-MAH/OMMT增韧母粒尺寸比较均匀,有少量POE-g-MAH进入OM MT片层之间,导致OMMT片层间距有所增加.POE-g-MAH/OMMT增...

关 键 词:POE-g-MAH/OMMT增韧母粒  尼龙6  缺口冲击强度

TOUGHENING MODIFICATION OF PA6 BY POE-g-MAH/OMMT TOUGHENING PARTICLE PREPARED BY BALL GRINDING METHOD
Wang Li,Xiong Yuzhu,Luo Jinzhong. TOUGHENING MODIFICATION OF PA6 BY POE-g-MAH/OMMT TOUGHENING PARTICLE PREPARED BY BALL GRINDING METHOD[J]. Engineering Plastics Application, 2011, 39(9): 26-29
Authors:Wang Li  Xiong Yuzhu  Luo Jinzhong
Affiliation:Wang Li,Xiong Yuzhu,Luo Jinzhong(College of Materials and Metallurgy,Guizhou University,Guiyang 550003,China;National Engineering Research Center for Compounding and Modification of Polymer Materials,Guiyang 550014,China)
Abstract:POE-g-MAH/OMMT toughening particles were prepared by ball grinding method and were used to modify the toughness of PA6.The results showed that the size of POE-g-MAH/OMMT particles prepared by ball grinding method was uniform.A small amount of POE-g-MAH get into the layers of OMMT,which increased the pitch of OMMT layers.The dispersion of POE-g-MAH/OMMT particles in PA6 matrix was better,but a slight agglomeration of particles occurred.With content of the POE-g-MAH/OMMT particles increasing,the notched impact strength of PA6/(POE-g-MAH/OMMT) blend increased.When the mass fraction of toughening particle exceed 15%,the mechanical properties of PA6/(POE-g-MAH/OMMT) blend were higher than PA6/POE-g-MAH blend.When the mass fraction of toughening particle was 15% and mass ratio of POE-g-MAH/OMMT was 80/20,the notched impact strength and tensile strength of PA6/(POE-g-MAH/OMMT) blend were highest.
Keywords:POE-g-MAH/OMMT toughening particle  PA6  notched impact strength
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