Dispersion study on third-order nonlinear optical properties of organic species with nitronyl nitroxide radical |
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Authors: | WENTAO HUANG SHUFENG WANG RUISHENG LIANG QIHUANG GONG DEQING ZHANG DAOBEN ZHU |
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Affiliation: | 1. State Key Laboratory for Mesoscopic Physics &2. Department of Physics, Peking University, Beijing 100871, PR China;3. Institute of Chemistry, Chinese Academy of Science, Beijing 100080, PR China |
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Abstract: | The third-order nonlinearity of five stable organic radical species with nitronyl nitroxide group was investigated using a femtosecond optical Kerr gate method. The magnitudes of their second hyperpolarizability were measured at around 10- 34 -10-32 esu. The influence of the subtle chemical change of the molecular structure was explored. The experimental results were compared with theoretical calculation. |
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