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Studies of coupled charge transport in dye-sensitized solar cells using a numerical simulation tool
Authors:Kristofer Fredin, Sven Rü  hle, Catelijne Grasso,Anders Hagfeldt,
Affiliation:aPhysical Chemistry, Royal Institute of Technology (KTH), Teknikringen 30/36, SE-10044 Stockholm, Sweden;bCondensed Matter and Interfaces, Debye Institute, Utrecht University, P.O. Box 80000, 3508 TA Utrecht, The Netherlands;cElectronics and Information Systems (ELIS), St. Pietersnieuwstraat 41, 9000 Gent, Belgium
Abstract:
In this paper, we present a simulation platform designed to study coupled charge transport in dye-sensitized solar cell (DSC) devices. The platform, SLICE, is used to study the influence of ions in the electrolyte on electron transport in the nanoporous medium. The simulations indicate that both cationic and anionic properties should be considered when modelling DSCs and similar systems. Additionally, it was found that the effective permittivity coefficient, ε, has no influence on the electron transport when the ionic concentration is sufficiently high due to the strong coupling between the respective charged species.
Keywords:Dye sensitized   Solar cell   Simulation   Charge transport   Model
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