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| 用DSC研究环氧树脂固化动力学 | |
| 引用本文： | 毛友安 童乙青. 用DSC研究环氧树脂固化动力学[J]. 高分子材料科学与工程, 1991, 7(3): 18-22 |
| 作者姓名： | 毛友安 童乙青 |
| 作者单位： | 国防科技大学材料科学与应用化学系，国防科技大学材料科学与应用化学系 长沙 410003，长沙 410003 |
| 摘 要： | 用等温DSC研究了双酚A二缩水甘油醚(E-51)与间苯二胺的固化动力学,探讨了固化机理,结果表明固化按自催化反应机理进行,体系中产生的羟基可加速反应。计算了固化反应各步的动力学参数,得到E_1=51.96kJ/mol,lnA_1=11.29,E_2=69.68kJ/mol,lnA_2=13.43。 |
| 关 键 词： | 环氧树脂 固化动力学 DSC |
A STUDY OF THE CURING KINETICS OF EPOXY RESIN BY DSC |
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| Mao Youan and Tong Yiqing. A STUDY OF THE CURING KINETICS OF EPOXY RESIN BY DSC[J]. Polymer Materials Science & Engineering, 1991, 7(3): 18-22 | |
| Authors: | Mao Youan and Tong Yiqing |
| Abstract: | The curing kinetics of bisphenol-A diglycidyl ether with m-phenylene diamine was studied by isothermal DSC. The mechanism of curing reaction was investigated. It was indicated that the curing reaction proceeds in auto-accelerated reacting mechanism and is accelerated by the hydroxyl groups produced in the system. The kinetics parameters of each step of curing reaction were calculated:E1=51.96kJ/mol , InA1=11,29 , E2=69.68kJ/mol and InA2=13.43. |
| Keywords: | epoxy resin curing kinetics DSC. |
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