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Metal oxide nanoparticles for advanced energy applications
Authors:Se-Hee Lee  Rohit. Deshpande  Phil A. Parilla  Anne C. Dillon
Affiliation:a Department of Mechanical Engineering, University of Colorado at Boulder, Boulder, CO 80309, USA
b National Renewable Energy Laboratory, 1617 Cole Boulevard, Golden, CO 80401, USA
Abstract:Hot-wire chemical vapor deposition (HWCVD) has been employed as an economically scalable method for the deposition of crystalline molybdenum oxide nanoparticles at high density. Under optimal synthesis conditions, only crystalline nanostructures with a smallest dimension of ~ 3-50 nm are observed with extensive transmission electron microscopy analyses. The incorporation of crystalline molybdenum oxide nanoparticles into battery electrodes has led to profound advancements in state-of-the-art negative electrodes (anodes) in lithium-ion batteries. The nanoparticle materials exhibit a high rate capability as anticipated for the reduced solid-state Li-ion diffusion length.
Keywords:Hot-wire chemical vapor deposition   Molybdenum oxide nanoparticles   Lithium-ion battery
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