Preparation of multilayered organic-inorganic hybrid core-shell particles by stepwise surface formation |
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Authors: | Takeshi Wakiya Tsuyoshi MorisakiNaoko Ishibashi Satomi NishimuraMakoto Takafuji Shoji NagaokaYasuyuki Yamada Shoji NozatoHirotaka Ihara |
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Affiliation: | a Department of Applied Chemistry and Biochemistry, Kumamoto University, Kumamoto 860-8555, Japanb Kumamoto Industrial Research Institute, Kumamoto 862-0901, Japanc Research & Development Institute, High Performance Plastics Company, Sekisui Chemical Co., Ltd., Osaka 618-00221 Japan |
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Abstract: | This paper introduces a stepwise formation method for micro-sized, multilayered core-shell particles comprising an inorganic core, organic inner shell, and inorganic outer shell. A silica core was coated with a polystyrene seed layer, followed by surface seed polymerization with styrene, to afford the inner shell. These particles were then coated with a silica outer shell by a surface sol-gel reaction with tetraethoxysilane. The versatility of this combined surface seed polymerization and sol-gel method is emphasized by the precise control achieved over particle diameter as well as shell thickness and count. Moreover, the organic inner shell can be readily eliminated to afford a single-core-containing micro-capsular structure. |
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Keywords: | Composite materials Core-shell particles Multilayer structure Organic-inorganic hybrids |
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