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Encapsulation of TiO2 by emulsion polymerization with methyl metacrylate (MMA)
Authors:Adriano Marim de Oliveira  Maria Lúcia Caetano Pinto da Silva  Gizelda Maria Alves  Pedro Carlos de Oliveira  Amilton Martins dos Santos
Affiliation:(1) Department of Chemical Engineering, Faculty of Chemical Engineering of Lorena, FAENQUIL, P.O. Box 116, Lorena, SP, Brazil
Abstract:Summary This paper presents a methodology of encapsulation of TiO2 (Titanium dioxide) by emulsion polymerization on the proposal to modify the physical-chemical properties of the pigment surface. In the proposed methodology the TiO2 was previously modified by isopropoxy-titanium-tri-isostearate, before being encapsulated by emulsion polymerization using Methyl Methacrylate as monomer. The effects of the polymerization process, type of initiator and monomer concentration in the efficiency of encapsulation were studied. The encapsulated pigment was characterized by Thermogravimetric Analysis (TGA), Light Scattering (LS) and Transmission Electron Microscopy (TEM).
Keywords:Titanium dioxide  methyl methacrylate  encapsulation  emulsion polymerization
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