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Novel pyrazoline-based selective fluorescent sensor for Zn in aqueous media
Authors:Zhong-Liang GongAuthor VitaeFei GeAuthor Vitae  Bao-Xiang ZhaoAuthor Vitae
Affiliation:Institute of Organic Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, PR China
Abstract:This work describes the preparation of a novel pyrazoline compound and the properties of its UV-vis absorption and fluorescence emission. Moreover, this compound can be used to determine Zn2+ ion with high selectivity and a low detection limit in the HEPES (20 mM HEPES, pH = 7.2, 50% (v/v) CH3CN) buffer solution. This sensor forms a 1:1 complex with Zn2+ and shows a fluorescent enhancement by chelation enhanced fluorescence effect with good tolerance of other metal ions. In addition, this sensor is very sensitive with fluorometric detection limit of 0.12 μM.
Keywords:Pyrazoline  Fluorescent sensor  Zinc ion detection  Selective
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