Novel pyrazoline-based selective fluorescent sensor for Zn in aqueous media |
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Authors: | Zhong-Liang GongAuthor VitaeFei GeAuthor Vitae Bao-Xiang ZhaoAuthor Vitae |
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Affiliation: | Institute of Organic Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, PR China |
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Abstract: | This work describes the preparation of a novel pyrazoline compound and the properties of its UV-vis absorption and fluorescence emission. Moreover, this compound can be used to determine Zn2+ ion with high selectivity and a low detection limit in the HEPES (20 mM HEPES, pH = 7.2, 50% (v/v) CH3CN) buffer solution. This sensor forms a 1:1 complex with Zn2+ and shows a fluorescent enhancement by chelation enhanced fluorescence effect with good tolerance of other metal ions. In addition, this sensor is very sensitive with fluorometric detection limit of 0.12 μM. |
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Keywords: | Pyrazoline Fluorescent sensor Zinc ion detection Selective |
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