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Chemical pathways for the polymerization of enines |
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| Authors: | Roberto Salcedo Takeshi Ogawa Armando Pineda Manuel F. Rubio-Arroyo Monserrat Garcia Patricia Guadarrama |
| Affiliation: | † Instituto de Investigaciones en Materiales, UNAM, Apartado Postal 70-360, 04510, Mexico DF, Mexico ‡ Instituto de Química UNAM, Apartado Postal 70-360, 04510, Mexico DF, Mexico § Facultad de Química, UNAM, Apartado Postal 70-360, 04510, Mexico DF, Mexico |
| Abstract: | AM1 calculations are reported for enines with aromatic substituents. It was found that the position of the unsaturated bonds in each molecule may account for the reactivity of each isomer via different polymerization pathways. The resonant structure of the charged form of one of the molecules allowed speculation about the observed inhibition of the polymerization reaction. |
| Keywords: | polymerization enines aromatic substituent |
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