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聚氨酯/三聚氰胺甲醛树脂复合泡沫热降解动力学研究
引用本文:相益信,冯绍华,冯厂.聚氨酯/三聚氰胺甲醛树脂复合泡沫热降解动力学研究[J].聚氨酯工业,2011,26(3):22-25.
作者姓名:相益信  冯绍华  冯厂
作者单位:青岛科技大学橡塑材料与工程教育部重点实验室,266042
摘    要:三聚氰胺甲醛树脂脱水后和多元醇混合,然后用异氰酸酯与混合物进行交联反应,生成聚氨酯/三聚氰胺甲醛树脂复合泡沫.热重分析结果表明,复合泡沫失重分为3个阶段,二苯基甲烷二异氰酸酯(MDI)型三聚氰胺甲醛树脂复合泡沫的第2阶段的失重峰温比甲苯二异氰酸酯(TDI)型三聚氰胺甲醛树脂复合泡沫的高.采用Kissinger法研究了该...

关 键 词:聚氨酯  三聚氰胺甲醛树脂  热失重分析  动力学

Study on the Kinetics of Thermal Decomposition of Polyurethane/Melamine Formaldehyde Resin Composite Foam
Xiang Yixin,Feng Shaohua,Feng Chang.Study on the Kinetics of Thermal Decomposition of Polyurethane/Melamine Formaldehyde Resin Composite Foam[J].Polyurethane Industry,2011,26(3):22-25.
Authors:Xiang Yixin  Feng Shaohua  Feng Chang
Affiliation:Xiang Yixin Feng Shaohua Feng Chang(Key Laboratory of Rubber-Plastics(QUST),Ministry of Education,Qingdao University of Science and Technology,266042,China)
Abstract:Melamine formaldehyde resin after dehydration and polyol were blended,and crosslinked by isocynante then composite foam was synthesized.The thermal stability of foams modified by polyurethane was studied by thermogravimetric analysis(TGA),and the results indicated that thermal degradation of the modified foams had three stages.The second decomposition temperatures of the foams modified by MDI type were much higher than the second decomposition temperatures of the foams modified by TDI type.The results from ...
Keywords:polyurethane  melamine formaldehyde resin  thermogravimetric analysis  kinetic  
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