| 微波辐射下空气氧化法合成2-(对甲氧基苯基)苯并咪唑 |
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| 引用本文： | 曹蒂薇,程国森,徐华诚,陈连清. 微波辐射下空气氧化法合成2-(对甲氧基苯基)苯并咪唑[J]. 化工科技, 2011, 19(6): 12-14 |
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| 作者姓名： | 曹蒂薇 程国森 徐华诚 陈连清 |
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| 作者单位： | 中南民族大学化学与材料科学学院,湖北武汉,430074 |
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| 基金项目： | 湖北省自然科学基金资助项目 |
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| 摘 要： | 首次在微波辐射下无催化剂空气直接氧化合成了2-(对甲氧基苯基)苯并咪唑,考察了微波辐射功率、辐射时间、原料配比、溶剂用量对产率的影响.实验表明:当微波辐射功率为280W,辐射时间为5.0min,n(对甲氧基苯甲醛):n(邻苯二胺)=1.1:1.0,乙醇用量为6.0mL时,产率可达88.7％.
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| 关 键 词： | 微波辐射 空气氧化法 2-(对甲氧基苯基)苯并咪唑 |
Synthesis of 2-(p-methoxyphenyl)-1H-benzo[d]imidazole under microwave irradiation by air oxidation method |
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| CAO Di-wei,CHENG Guo-sen,XU Hua-cheng,CHEN Lian-qing. Synthesis of 2-(p-methoxyphenyl)-1H-benzo[d]imidazole under microwave irradiation by air oxidation method[J]. Science & Technology In Chemical Industry, 2011, 19(6): 12-14 |
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| Authors: | CAO Di-wei CHENG Guo-sen XU Hua-cheng CHEN Lian-qing |
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| Affiliation: | (College of Chemistry and Materials Science,South-Central University for Nationalities,Wuhan 430074,China) |
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| Abstract: | 2-（p-Methoxyphenyl）-1H-benzo[d]imidazole was efficiently synthesized from p-methoxybenzaldehyde and o-phenylenediamine under microwave irradiation by air oxidation method without any catalyst for the first time.The effects of microwave irradiation power,microwave irradiation time,molar ratio,and solvent amount on the yield of object compound were investigated.The results showed that the optimum reaction conditions are as follows：microwave irradiation power 280 W,radiation time 5.0 min,n（p-methoxybenzaldehyde）∶n（o-phenylenediamine） = 1.1∶1.0,amount of ethanol 6.0 mL,the highest yield of the title compound was up to 88.7%. |
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| Keywords: | Microwave irradiation Air oxidation method 2-（p-Methoxyphenyl）-1H-benzo[d]imidazole |
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