| 几种对称钕卟啉配合物的固相合成及电化学性质 |
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| 引用本文： | 郑瑛,邱健斌,项生昌,刘云珍.几种对称钕卟啉配合物的固相合成及电化学性质[J].稀土,2002,23(1):17-19. |
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| 作者姓名： | 郑瑛 邱健斌 项生昌 刘云珍 |
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| 作者单位： | 福建师范大学,化学系,福建,福州,350007 |
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| 基金项目： | 福建省教委资助课题 ( JB990 0 2 ) |
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| 摘 要： | 在固相条件下合成了四苯基卟啉钕、四 (对羟基苯基 )卟啉钕、四 (对甲氧基苯基 )卟啉钕、四 (对硝基苯基 )卟啉钕四种钕卟啉配合物。并用元素分析、ICP、U V、IR等手段对配合物进行了表征。用循环伏安法研究了它们的电化学性质。实验结果表明 :四种钕卟啉配合物的电化学性质相似。在循环伏安图上均出现了三对氧化还原电位。但由于卟啉环上对位取代基不同 ,峰电位值不同
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| 关 键 词： | 钕卟啉 固相 电化学 |
| 文章编号： | 1004-0277(2002)01-0017-03 |
| 修稿时间： | 2001年9月5日 |
Solid State Synthesis and Electrochemical Behavior of Neodymium Porphyrins |
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| ZHENG Ying,QIU Jian bin,XIANG Sheng chang,LIU Yun zhen.Solid State Synthesis and Electrochemical Behavior of Neodymium Porphyrins[J].Chinese Rare Earths,2002,23(1):17-19. |
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| Authors: | ZHENG Ying QIU Jian bin XIANG Sheng chang LIU Yun zhen |
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| Abstract: | Neodymium porphyrins rare earth elements complexes were synthesized by solid state reaction The products were characterized by elementary analysis,ICP,UV-Vis and IR The eletrochemical behavior of complexes were investigated by cyclic voltammetry in DMSO The results showed that the electrochemical behavior of neodymium porphyrins complexes were similar There were three inreversible steps |
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| Keywords: | neodymium porphyrin solid state reaction electrochemistry |
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