A study of the oxidation kinetics of CuFeO2 in the Cu-Fe-O system

The oxidation kinetics of CuFeO₂ in the Cu-Fe-O system have been studied between 500 and 900° C in an atmosphere containing 1 vol% oxygen in a nitrogen stream using thermogravimetric analysis (TGA). It was found that addition of Fe₂O₃ to the CuFeO₂ caused a decrease in the oxidation rate while addition of CuO caused an increase. On increasing the concentration of Fe₂O₃ the activation energy was found to increase from ~ 18 kcal mol^–1 to ~ 45 kcal mol^–1 and the exponent n in Avrami's equationf=1-exp (–ktⁿ) was also observed to increase, from 1.3 to 2.3. On adding CuO to the CuFeO₂ in the Cu-Fe-O system the activation energy decreased from ~ 18 kcal mol^–1 to ~ 8 kcal mol^–1. The variation in both values indicates changes in the oxidation mechanisms. The microstructural changes associated with oxidation have been studied using optical microscopy. A model has been proposed to explain the results.