| 生物质催化热解的TG-FTIR研究 |
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| 引用本文： | 鲁长波,杨昌炎,林伟刚,姚建中,杨学民,宋文立.生物质催化热解的TG-FTIR研究[J].太阳能学报,2007,28(6):638-643. |
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| 作者姓名： | 鲁长波 杨昌炎 林伟刚 姚建中 杨学民 宋文立 |
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| 作者单位： | 1. 中国科学院过程工程研究所多相重点实验室,北京,100080;中国科学院研究生院,北京,100080
2. 中国科学院过程工程研究所多相重点实验室,北京,100080 |
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| 基金项目： | 国家重点基础研究发展计划(973计划) |
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| 摘 要： | 借助综合热分析仪和傅立叶红外联用技术(TG-FTIR),考察了HUSY、REY和HZSM-53种分子筛以及重油催化裂化催化剂MLC和馏分油催化裂解催化剂CIP对生物质催化热解的活性和选择性。研究结果表明,分子筛对生物质热解产物的脱氧活性顺序为:REY≈HUSY>HZSM-5,生成高辛烷值烃类的选择性顺序为:REY>HUSY≈HZSM-5;MLC催化剂和CIP催化剂都表现出较高的选择活性,前者的脱氧活性略高于后者;择形分子筛HZSM-5的引入对调整催化剂酸强度、提高催化转化选择性和抑制焦炭生成产生一定作用。
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| 关 键 词： | 生物质 催化热解 活性 选择性 分子筛 |
| 文章编号： | 0254-0096（2007）06-0638-06 |
| 修稿时间： | 2006-03-01 |
TG-FTIR RESEARCH OF BIOMASS CATALYTIC PYROLYSIS |
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| Lu Changbo,Yang Changyan,Lin Weigang,Yao Jianzhong,Yang Xuemin,Song Wenli.TG-FTIR RESEARCH OF BIOMASS CATALYTIC PYROLYSIS[J].Acta Energiae Solaris Sinica,2007,28(6):638-643. |
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| Authors: | Lu Changbo Yang Changyan Lin Weigang Yao Jianzhong Yang Xuemin Song Wenli |
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| Affiliation: | 1. Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080, China; 2. Gradwate School of Chinese Academy of Sciences, Beijing 100080, China |
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| Abstract: | The TG integrated with FTIR was used to investigate the activities and selectivities of HUSY,REY and HZSM- 5 zeolites,and furthermore,the heavy oil cracking catalyst MLC and distillate oil cracking catalyst CIP used in China re- fining industry.The research shows that REY zeolite has satisifing activity for deoxygenation and selectivity for High-Oc- tane-Number-Hydrocarbons production.Both MLC and CIP catalyst show well HONH selectivities,however,MLC cata- lyst shows better deoxygenating activity.The adoption of HZSM-5 can adjust catalyst acid strength,improve catalyst se- lectivity and inhabit the coke-deposition on catalyst pores as well. |
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| Keywords: | TG-FTIR |
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