Melt‐state miscibility of poly(ethylene‐co‐1‐octene) and linear polyethylene |
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Authors: | Kyusoon Shin Byeong Uk Nam Joona Bang Jae Young Jho |
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Affiliation: | 1. School of Chemical and Biological Engineering, Seoul National University, Shinlim, Kwanak, Seoul 151‐742, Republic of Korea;2. Department of Applied Chemical Engineering, Korea University of Technology and Education, Chongnam, 330‐708, Republic of Korea;3. Department of Chemical and Biological Engineering, Korea University, Anam, Seoul 136‐701, Republic of Korea |
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Abstract: | On purpose to examine the effect of branch length on the miscibility of polyolefin blends, miscibility behavior of linear polyethylene/poly(ethylene‐co‐1‐octene) blend was studied and compared to that of linear polyethylene/poly(ethylene‐co‐1‐butene) blend. Miscibility of the blend was determined by observing the morphology quenched from the melt, and by using the relation between interaction parameter and copolymer composition. When the weight composition and molecular weight was the same, poly(ethylene‐co‐1‐octene) was slightly more miscible with linear polyethylene than poly(ethylene‐co‐1‐butene) was. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 |
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Keywords: | polyolefins blends miscibility |
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