An in situ approach to synthesize pure phase FAU-type zeolite membranes: effect of aging and formation mechanism |
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Authors: | Guangqi Zhu Yanshuo Li Hongliang Chen Jie Liu Weishen Yang |
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Affiliation: | (1) State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, 116023, China;(2) Graduate School of Chinese Academy of Sciences, Beijing, 100049, China |
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Abstract: | FAU-type zeolite membranes were prepared on porous α-Al2O3 tubes by a two-stage in situ synthesis method. The synthesis was carried out in clear solutions without the aid of seeds
or organic templates. The first stage synthesis was devoted to the in situ nucleation of FAU-type zeolite, aiming to induce
an evenly covered zeolite layer on the support. In situ aging played an important role at this stage as it suppressed LTA
phase and promoted the formation of a continuous zeolite layer. The second stage synthesis was performed in a dilute solution,
where the pre-formed zeolite layer went on to grow and became compact. Scanning electron microscopy (SEM) observations show
that the membranes were made up of well-shaped intergrown crystals, with the thickness around 7 μm. Pervaporation (a membrane-based
separation process in which the liquid components diffuse through a membrane and are subsequently vaporized due to the low-pressure
exerted on the permeate side of the membrane) measurements were carried out in a water/ethanol (10/90, w/w) mixture to evaluate
the membrane performance. The structural and morphological evolutions of FAU-type zeolite membranes during synthesis were
tracked down by X-ray diffraction and SEM. The formation mechanism was illuminated based on the experimental results. |
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