| 纳米枝状聚苯胺的合成及其电催化性能研究 |
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| 引用本文： | 龚建华,赵丹,陶菲菲.纳米枝状聚苯胺的合成及其电催化性能研究[J].广东化工,2010,37(1):115-117. |
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| 作者姓名： | 龚建华 赵丹 陶菲菲 |
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| 作者单位： | 绍兴文理学院化学化工学院,浙江绍兴,312000 |
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| 基金项目： | 浙江省教育厅科研项目(Y200805544);;2008年度浙江省高校优秀青年教师资助计划;;绍兴文理学院大学生科研基金资助项目 |
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| 摘 要： | 文章采用化学氧化聚合法成功地合成了纳米枝状聚苯胺,该方法简单,反应条件温和。通过透射电子显微镜(TEM)、傅立叶变换红外光谱仪(FTIR)和X射线衍射(XRD)等方法对产物的形貌和晶相进行了表征;循环伏安实验表明纳米枝状聚苯胺修饰电极对抗坏血酸有优异的电催化活性,与裸玻碳电极相比,抗坏血酸的氧化峰电位负移0.263 V,氧化峰电流增大46%;抗坏血酸浓度在1.0×10-5～0.1 M范围内呈良好线性关系,最低检测限为1.0×10-6 M。
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| 关 键 词： | 聚苯胺 枝状结构 电催化 |
Fabrication and Electrocatalytic Properties of Dendrite-Like Polyaniline Nanomaterials |
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| Gong Jianhua,Zhao Dan,Tao Feifei.Fabrication and Electrocatalytic Properties of Dendrite-Like Polyaniline Nanomaterials[J].Guangdong Chemical Industry,2010,37(1):115-117. |
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| Authors: | Gong Jianhua Zhao Dan Tao Feifei |
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| Affiliation: | School of Chemistry and Chemical Engineering;Shaoxing University;Shaoxing 312000;China |
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| Abstract: | The paper described the successful fabrication of nano-dendrite-like polyaniline by the chemical oxidation polymerization method,which was simple and gentle.Through transmission electron microscope(TEM),Fourier transform IR(FTIR) and X-ray diffraction(XRD),the morphologies and structure of dendrite-like polyaniline were characterized.The cyclic voltammetry experiments showed that the nano-dendrite-like polyaniline modified electrode expressed an excellent activity of electrocatalysis on ascorbic acid(AA).In... |
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| Keywords: | polyaniline dendrite-like structure electrocatalysis |
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