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| 室温熔盐在碳纳米管电化学电容器中的应用 | |
| 引用本文： | 陈人杰,吴锋,徐斌,苏岳锋,邱新平.室温熔盐在碳纳米管电化学电容器中的应用[J].电子元件与材料,2007,26(4):11-14. |
| 作者姓名： | 陈人杰 吴锋 徐斌 苏岳锋 邱新平 |
| 作者单位： | 1. 清华大学化学系,北京,100084;北京理工大学化工与环境学院,北京,100081 2. 北京理工大学化工与环境学院,北京,100081 3. 清华大学化学系,北京,100084 |
| 基金项目： | 国家重点基础研究发展计划(973计划) |
| 摘 要： | 将碳纳米管制成薄膜电极,以二(三氟甲基磺酸酰)亚胺锂(LiTFSI)-1,3-氮氧杂环戊-2-酮(OZO)室温熔盐为电解液,装配成模拟电容器。测试结果表明,比电容为20.5F/g,工作电压可达2.0V以上,循环充放电500次后容量损失小于5%。室温熔盐在碳纳米管电化学电容器中表现出良好的电化学兼容性,具有良好的热稳定性,是超级电容器非常有前景的新型电解液。 |
| 关 键 词： | 电子技术 室温熔盐 碳纳米管 电解质 电容器 |
| 文章编号： | 1001-2028（2007）04-0011-04 |
| 修稿时间： | 2007-01-18 |
Application of room temperature molten salt as electrolyte for electrochemical capacitor based on carbon nanotube |
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| CHEN Ren-jie,WU Feng,XU Bin,SU Yue-feng,QIU Xin-ping.Application of room temperature molten salt as electrolyte for electrochemical capacitor based on carbon nanotube[J].Electronic Components & Materials,2007,26(4):11-14. | |
| Authors: | CHEN Ren-jie WU Feng XU Bin SU Yue-feng QIU Xin-ping |
| Abstract: | The test capacitors composed of a pair of carbon nanotubes electrodes and the room temperature molten salt (RTMS) based on lithium bis(trifluoromethane sulfone)imide (LiN(SO2CF3)2, LiTFSI) with 2-oxazolidinone (C3H5NO2, OZO) as electrolyte were assembled. A high specific capacitance of 20.5 F/g estimated by galvanostatic charge/discharge measurement is obtained. The working voltage of the test capacitors reach above 2.0 V. After 500 charge and discharge cycles, the capacity loss is just 5 % of the initial discharge capacity. The RTMS show good electrochemical compatibility and high thermal stability in the capacitor based on carbon nanotube. The results demonstrate that the RTMS is the promising electrolyte candidate for supercapacitors. |
| Keywords: | electron technology room temperature molten salt carbon nanotubes electrolyte capacitors |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |