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Viscosity of nonelectrolyte liquid mixtures. III Binary mixtures of methyl methacrylate with hydrocarbons,haloalkanes, and alkylamines
Authors:Oswal  S. L.  Patel  B. M.  Shah  H. R.  Oswal  P.
Affiliation:(1) Department of Chemistry, South Gujarat University, 395007 Surat, India;(2) Department of Chemistry, Government College, 312605 Pratabgarh, India
Abstract:Measurements of the viscosityeegr and the densityrhov are reported for 14 binary mixtures of methyl methacrylate (MMA) with hydrocarbons, haloalkanes, and alkylamines at 303.15 K. The viscosity data have been correlated with equations of Grunberg and Nissan, of McAllister, and of Auslaender. Furthermore, excess viscosityDelta Ineegr and excess Gibbs energy of activationDeltaG*E of viscous flow have been calculated and have been used to predict molecular interactions occurring in present binary mixtures. The results show the existence of specific interactions in MMA + aromatic hydrocarbons, MMA + haloalkanes, and MMA + primary amines.
Keywords:Alkylamine  aromatic hydrocarbons  binary liquid mixtures  cyclohexane  density  Gibbs energy of activation  haloalkanes    /content/m188177vq41x9x24/xxlarge951.gif"   alt="  eegr"   align="  MIDDLE"   BORDER="  0"  >-hexane  molecular interactions  viscosity
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