Viscosity of nonelectrolyte liquid mixtures. III Binary mixtures of methyl methacrylate with hydrocarbons,haloalkanes, and alkylamines |
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Authors: | Oswal S. L. Patel B. M. Shah H. R. Oswal P. |
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Affiliation: | (1) Department of Chemistry, South Gujarat University, 395007 Surat, India;(2) Department of Chemistry, Government College, 312605 Pratabgarh, India |
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Abstract: | Measurements of the viscosity and the density are reported for 14 binary mixtures of methyl methacrylate (MMA) with hydrocarbons, haloalkanes, and alkylamines at 303.15 K. The viscosity data have been correlated with equations of Grunberg and Nissan, of McAllister, and of Auslaender. Furthermore, excess viscosity In and excess Gibbs energy of activation G*E of viscous flow have been calculated and have been used to predict molecular interactions occurring in present binary mixtures. The results show the existence of specific interactions in MMA + aromatic hydrocarbons, MMA + haloalkanes, and MMA + primary amines. |
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Keywords: | Alkylamine aromatic hydrocarbons binary liquid mixtures cyclohexane density Gibbs energy of activation haloalkanes /content/m188177vq41x9x24/xxlarge951.gif" alt=" eegr" align=" MIDDLE" BORDER=" 0" >-hexane molecular interactions viscosity |
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