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Investigation on energy transfer from Er^3+ to Nd^3+ in tellurite glass
引用本文:沈祥,聂秋华,徐铁峰,戴世勋,王训四. Investigation on energy transfer from Er^3+ to Nd^3+ in tellurite glass[J]. 中国稀土学报(英文版), 2008, 26(6): 899-903. DOI: 10.1016/S1002-0721(09)60029-6
作者姓名:沈祥  聂秋华  徐铁峰  戴世勋  王训四
作者单位:Faculty of Information Science and Engineering, Ningbo University, Ningbo 315211, China
基金项目:Project supported by the Natural Science Foundation of Zhejiang Province (2006C21082) and the Education Department Project of Zhejiang Province (20061664)
摘    要:
A study of energy transfer of Er^3+/Nd^3+ codoped tellurite glasses was presented. By Nd^3+ co-doping, both the Er^3+ green emission corresponding to the Er^3+: (^4S3/2, ^2H11/2)→^4I15/2 transitions and the red emission corresponding to the Er^3+: ^4F9/2→^4I15/2 transitions were quenched. The energy transfer mechanism between Er^3+ and Nd^3+ was discussed based on their energy level characteristics. The interaction parameters, CO-A, for the energy transfer processes from Er^3+ to Nd^3+ in tellurites glass were calculated. Finally, the resonant transfer Er^3+: ^4I9/2→Nd^3+: (^4F5/2, ^2H9/2) was proposed to be the most probable microscopic process to occur in contrast with the other processes.

关 键 词:能量转换  亚碲酸玻璃  双掺杂  稀土
收稿时间:2007-08-05

Investigation on energy transfer from Er to Nd in tellurite glass
Xiang SHEN, Qiuhua NIE, Tiefeng XU, Shixun DAI,Xunsi WANG. Investigation on energy transfer from Er to Nd in tellurite glass[J]. Journal of Rare Earths, 2008, 26(6): 899-903. DOI: 10.1016/S1002-0721(09)60029-6
Authors:Xiang SHEN   Qiuhua NIE   Tiefeng XU   Shixun DAI  Xunsi WANG
Affiliation:aFaculty of Information Science and Engineering, Ningbo University, Ningbo 315211, China
Abstract:
A study of energy transfer of Er3+/Nd3+ codoped tellurite glasses was presented. By Nd3+ co-doping, both the Er3+ green emission corresponding to the Er3+: (4S3/2, 2H11/2) → 4I15/2 transitions and the red emission corresponding to the Er3+: 4F9/24I15/2 transitions were quenched. The energy transfer mechanism between Er3+ and Nd3+ was discussed based on their energy level characteristics. The interaction parameters, CD-A, for the energy transfer processes from Er3+ to Nd3+ in tellurites glass were calculated. Finally, the resonant transfer Er3+: 4I9/2 → Nd3+: (4F5/2, 2H9/2) was proposed to be the most probable microscopic process to occur in contrast with the other processes.
Keywords:energy transfer   tellurite glass   rare earths
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