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New Ru-Based Layered Cuprates with 1232 Structure in the RuSr2(LnCe2−x Sr x )Cu2O z (Ln = Sm, Eu, and Gd) System
Authors:H. Sasakura  Y. Akagi  S. Noguchi  S. Tsukui  T. Oka  M. Adachi
Affiliation:1. Department of Physics, Hamamatsu University School of Medicine, 1-20-1 Handayama, Hamamatsu, Shizuoka, 431-3192, Japan
2. Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka, 599-8531, Japan
3. Research Institute for Advanced Science and Technology, Osaka Prefectre University, Sakai, Osaka, 599-8570, Japan
Abstract:New Ru-based layered cuprates with 1232 structure have been synthesized in the RuSr2(LnCe2?x Sr x )Cu2O z (Ln = Sm, Eu, and Gd) system. Nearly single-phase samples are obtained in the composition range from x = 0.0 to 0.2 for Ln = Sm and Eu, and at the composition of x = 0.2 for Ln = Gd. Each of the samples of Ln = Sm, Eu, and Gd with x = 0.2 crystallizes in a tetragonal lattice and lattice parameters a and c are 0.3845 and 1.700 nm, 0.3842 and 1.699 nm, and then 0.3839 and 1.698 nm, respectively. Each of them shows some anomalies at a low temperature in addition to a semiconductor-like temperature dependence of the resistivity. Especially, the sample with Ln = Gd shows two resistivity dropping phenomena at about 16 and 22 K. Then, all of nearly single-phase samples show diamagnetic signals originating from superconductivity, and also rapid increase of magnetization due to a transition from paramagnetic state to ferromagnetic one below 80 K.
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