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两亲性接枝物CPE-g-AM-MAH的合成条件研究
引用本文:张飞,张玉红,何培新.两亲性接枝物CPE-g-AM-MAH的合成条件研究[J].胶体与聚合物,2011,29(1):25-27.
作者姓名:张飞  张玉红  何培新
作者单位:湖北大学化学化工学院,湖北武汉,430062
基金项目:湖北自然科学基金,武汉市重点科技攻关项目,湖北省科技攻关引导项目
摘    要:采用悬浮溶胀法将丙烯酰胺(AM)、马来酸酐(MAH)与氯化聚乙烯(CPE)进行接枝反应,制备得到了两亲性共聚物(CPE-g-AM-MAH),用红外光谱对接枝物结构进行了表征,利用正交试验法讨论了氯化聚乙烯、马来酸酐、AM/MAH比率、引发剂对接枝率和接枝效率的影响.结果表明:各影响因素对接枝率的影响顺序为AM>CPE>...

关 键 词:氯化聚乙烯  丙烯酰胺  马来酸酐  正交实验

Study on the Synthesis Condition for the Amphiphilic Graft Copolymer CPE-g-AM-MAH
ZHANG Fei,ZHANG Yuhong,HE Peixin.Study on the Synthesis Condition for the Amphiphilic Graft Copolymer CPE-g-AM-MAH[J].Chinese Journal of Colloid and Polymer,2011,29(1):25-27.
Authors:ZHANG Fei  ZHANG Yuhong  HE Peixin
Affiliation:ZHANG Fei,ZHANG Yuhong,HE Peixin*(College of Chemistry and Chemical Engineering,Hubei University,Wuhan 430062)
Abstract:The amphiphilic graft copolymer CPE-g-AM-MAH was prepared by grafting copolymerization of acrylamide(AM) and maleic anhydride(MAH) onto chlorinated polyethylene(CPE) through swelling suspension polymerization.The graft copolymer was characterized by infrared spectroscopy(IR).And the effects of polymerization conditions,including the CPE,maleic anhydride,initiator amount,the mass ratio AM/MAH on graft degree and graft efficiency have been investigated using orthogonal experiment method.It can be concluded th...
Keywords:Chlorinated Polyethylene  Maleic Anhydride  Acrylamide  Orthogonal Experiment  
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