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PAN/PPG纤维预氧化及碳纤维结构和性能研究
引用本文:黄金元,杜赞格,陈惠芳,潘鼎.PAN/PPG纤维预氧化及碳纤维结构和性能研究[J].高科技纤维与应用,2011,36(1):24-27,31.
作者姓名:黄金元  杜赞格  陈惠芳  潘鼎
作者单位:东华大学材料科学与工程学院,高性能纤维及制品教育部重点实验室,上海,201620
基金项目:上海市基础研究重大项目(07DJ14002); 高等学校科技创新引智计划资助项目(111-2-04)
摘    要:采用聚丙二醇(PPG)与聚丙烯腈(PAN)共混制备的PAN/PPG原丝进行预氧化和碳化,利用SEM、FTIR、元素分析仪、力学性能测试等仪器和手段,研究了PPG的加入对预氧丝和碳丝的结构和性能的影响.研究发现:PPG的加入使PAN预氧丝的表面结构更加均匀,减少了碳纤维中的孔洞;同时还促进了纤维在预氧化和碳化过程中的氧化...

关 键 词:聚丙烯腈  聚丙二醇  预氧丝  碳纤维  结构  性能

Pre-oxidation of PAN/PPG fiber and structure-property relation of carbon fibers
Huang Jin-yuan,Du Zang-e,Chen Hui-fang,Pan Ding.Pre-oxidation of PAN/PPG fiber and structure-property relation of carbon fibers[J].Hi-Tech Fiber & Application,2011,36(1):24-27,31.
Authors:Huang Jin-yuan  Du Zang-e  Chen Hui-fang  Pan Ding
Affiliation:Huang Jin-yuan,Du Zang-e,Chen Hui-fang,Pan Ding(The Key Laboratory of High-Performance Fibers and Products Ministry of Education,College of Materials Sci- ence and Engineering,Donghua University,Shanghai 201620)
Abstract:PAN/PPG precursors were pre-oxidized and carbonized,the influences of PPG on the structures and properties of the pre-oxidized and carbonized PAN fibers were studied by SEM,FTIR,elemental analysis and me-chanical testing.The results indicated that,with the introduction of PPG,the pre-oxidized fiber surfaces became more homogeneous and the carbon fibers interior holes decreased;The addition of PPG also enhanced the oxida-tion reactions during pre-oxidation and carbonation processes,and the mechanical propert...
Keywords:PAN  PPG  pre-oxidized fiber  carbon fiber  
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