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Influence of two-step ball-milling condition on electrical and mechanical properties of TiC-dispersion-strengthened Cu alloys
Affiliation:1. Department of Materials Processing, Tohoku University, Sendai 980-8579, Japan;2. Institute for Materials Research, Tohoku University, Sendai 980-0812, Japan;1. International Advanced Research Centre for Powder Metallurgy and New Materials (ARCI), Balapur P.O., Hyderabad, 500 005, India;2. Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai, 400 076, India;1. School of Energy, Power and Mechanical Engineering, North China Electric Power University, Baoding 071003, PR China;2. College of Mechanical and Electric Engineering, Hebei Agricultural University, Baoding 071001, PR China;1. Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), Northeastern University, Shenyang 110819, China;2. Institute of Ceramics and Powder Metallurgy, School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China;3. Australian Nuclear Science and Technology Organization, Lucas Heights, NSW 2234, Australia;4. The State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;5. Shanghai Institute of Applied Physics, Chinese Academy of Sciences (CAS), Shanghai 201800, China;1. School of Materials Science and Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, PR China;2. Institute of Engineering Research, Jiangxi University of Science and Technology, Ganzhou 341000, PR China
Abstract:TiC-dispersion-strengthened Cu alloys were prepared by a two-step ball-milling (BM) process followed by sparks plasma sintering (SPS), heat treatment and hot rolling in sequence. The two-step BM process is composed of a pre-ball-milling (pre-BM) on both Ti and graphite powders as well as a subsequent homogenizing by BM together with Cu powder. Microstructure evolution analysis was performed to evaluate the effects of BM conditions on the electrical and mechanical properties of Cu-based alloys. The X-ray results revealed that titanium carbide (TiC) formed from Ti and C under high impact energy BM. Moreover, the formation of TiC during the SPS and heat treatment processes was found to more beneficial in enhancing the mechanical properties of alloy. The residual Ti in Cu matrix was found to be the predominant factor lowering the electrical conductivity of Cu–Ti–C alloys.
Keywords:Two-step ball-milling  Dispersion-strengthened copper alloy  In-situ reaction
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