| 原子转移自由基聚合进展及其在新型聚合物制备中的应用 |
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| 引用本文： | 苏永锋. 原子转移自由基聚合进展及其在新型聚合物制备中的应用[J]. 化学推进剂与高分子材料, 2010, 8(2): 38-41 |
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| 作者姓名： | 苏永锋 |
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| 作者单位： | 广东工业大学轻工化工学院.广东广州,510006 |
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| 摘 要： | 概述了原子转移自由基聚合(ATRP)的机理及其在引发体系、单体、反应温度和介质等方面的进展;着重论述了ATRP在进行聚合物分子设计,制备具有特定结构的聚合物,如无规、梯度和交替共聚物,嵌段共聚物,末端官能团聚合物,接枝和梳状聚合物,星型高支化聚合物等方面的应用。
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| 关 键 词： | 原子转移自由基聚合 进展 聚合物分子设计 应用 |
Progress of Atom Transfer Radical Polymerization and Its Application in Preparation of Novel Polymers |
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| SU Yong-feng. Progress of Atom Transfer Radical Polymerization and Its Application in Preparation of Novel Polymers[J]. Chemical Propellants & Polymeric Materials, 2010, 8(2): 38-41 |
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| Authors: | SU Yong-feng |
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| Affiliation: | Faculty of Chemical Engineering and Light Industry;Guangdong University of Technology;Guangzhou 510006;China |
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| Abstract: | The mechanism of atom transfer radical polymerization(ATRP) and the progresses of its initiator system, monomers, reaction temperature, medium, etc. are summarized. The applications of ATRP in polymer molecule design, preparation of polymers with specific structure, such as random copolymer, gradient copolymer, alternative copolymer, block copolymer, functional-terminated polymer, graft copolymer, comb-shaped polymer, star-shaped hyperbranched polymer and so on are emphatically reviewed. |
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| Keywords: | atom transfer radical polymerization progress polymer molecule design application |
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