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Removal of Sulfur from CaF2 Containing Desulfurization Slag Exhausted from Secondary Steelmaking Process by Oxidation
Authors:Takehito Hiraki  Junichi Kobayashi  Satomi Urushibata  Kazuyo Matsubae  Tetsuya Nagasaka
Affiliation:1. Graduate School of Engineering, Tohoku University, Sendai, 980-8579, Japan
2. Sumitomo Mining Co., Ltd., Tokyo, 105-8716, Japan
3. Kobe Steel Co., Ltd., Tokyo, 651-8585, Japan
Abstract:The oxidation behavior of sulfur in desulfurization slag generated from the secondary steelmaking process with air has been investigated in the temperature range of 973?K to 1373?K (700?°C to 1100?°C). Although a high removal rate of sulfur is not achieved at temperatures lower than 1273?K (1000?°C) because of the formation of CaSO4, most of the sulfur is rapidly removed from slag as SO2 gas in the 1273?K to 1373?K (700?°C to 1100?°C) range. This finding indicates that the desulfurization slag generated from the secondary steelmaking process can be reused as a desulfurized flux through air oxidation, making it possible to reduce significantly the amount of desulfurization slag for disposal.
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