Characterization of carbon/carbon composite/Ti6Al4V joints brazed with graphene nanosheets strengthened AgCuTi filler |
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| Affiliation: | 1. State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001, China;2. Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209, China;3. Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518000, China;1. School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China;2. National-Local Joint Engineering Research Center of Nonferrous Metals and Processing Technology, Hefei University of Technology, Hefei 230009, China;1. State Key Laboratory of Solidification Processing, Carbon/Carbon Composites Research Center, Northwestern Polytechnical University, Xi׳an 710072, China;2. Applied Science and Technology Department, Politecnico di Torino, Corso Duca degli Abruzzi, 24, Torino I-10129 , Italy |
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| Abstract: | ![]()
Carbon/carbon (C/C) composite and Ti6Al4V alloy (wt%) were successfully brazed with graphene nanosheets strengthened AgCuTi filler (AgCuTiG). Graphene nanosheets (GNSs) with low CTE and high strength were dispersed into AgCuTi filler by ball milling. The interfacial microstructure was systematically characterized by varieties of analytical means including transmission electron microscopy (TEM). Results show that typical interfacial microstructure of the joint brazed at 880 °C for 10 min is a layer structure consisting of (Ti6Al4V/diffusion layer/Ti2Cu + TiCu + Ti3Cu4 + TiCu4/GNSs + TiCu + TiC + Ag(s,s) + Cu(s,s)/TiC/C/C composite). The interfacial microstructure and mechanical properties of brazed joints changed significantly as temperature increased. High temperature promoted the growth of TiCu and TiC phases, which were attached to GNSs. Meanwhile, the diffusion layer and primary reaction layers thickened as temperature increased, while the thickness of brazing seam decreased. The maximum shear strength of 30.2 MPa was obtained for the joint brazed at 900 °C for 10 min. GNSs decreased the thickness of brittle reaction layers and promoted the formation of TiCu and TiC phases in brazing seam, which caused the strengthening effect and decreased the CTE mismatch of brazed joints. The fracture modes are also discussed in this paper. |
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| Keywords: | C/C composite Composite filler Microstructure Mechanical property |
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