Reduced graphene oxide–poly(methyl methacrylate) nanocomposite as a supercapacitor |
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Authors: | Zabiholah Zabihi Paul Eduardo David Soto Rodriguez Abderrahmane Boujakhrout Juan Carlos Viera Jorge Alonso del Valle Houshang Araghi Reynaldo Villalonga |
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Affiliation: | 1. Department of Physics, Amirkabir University of Technology, Tehran, Iran;2. Department of Analytical Chemistry, Universidad Complutense de Madrid, Ciudad Universitaria s/n 28040, Madrid, Spain;3. Departament of Electrical and Electronic Engineering, University of Oviedo, Campus de Viesques, s/n, Edificio Departamental 3 33204, Gijón Asturias, Spain |
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Abstract: | An exhaustive study on a nanocomposite–poly(methyl methacrylate) matrix material as a supercapacitor is presented. The study includes morphological, structural, and electrochemical characterization. Different electrolytes were used, for which both pseudocapacitance (for reduced graphene oxide) and electric double‐layer capacitance (for functionalized graphene) were observed. An optimum nanocomposite weight percentage was found (2%), and the best performance with highest capacitance (30.4 F/g) was seen for the electrolyte including the smallest anions (OH?), being among the best values for similar systems, that is, a nanocomposite/nonconductive polymer matrix. In addition, a model is presented that explains the underlying electron transport mechanism. The results are promising for the construction of supercapacitors based on novel nanocomposite–poly(methyl methacrylate) matrix materials. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46685 |
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Keywords: | batteries and fuel cells electrochemistry fullerenes graphene nanotubes |
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