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Enhancement of Seebeck coefficient of mesoporous SrTiO3 with V-group elements V,Nb, and Ta substituted for Ti
Authors:Chang-Sun Park  Min-Hee Hong  Hyung Hee Cho  Hyung-Ho Park
Affiliation:1. Department of Materials Science and Engineering, Yonsei University, Seoul 03722, Republic of Korea;2. School of Mechanical Engineering, Yonsei University, Seoul 03722, Republic of Korea
Abstract:The carrier concentration and effective mass of mesoporous SrTiO3 films were controlled by the substitution of Ti with V-group elements (V, Nb, and Ta) to enhance the thermoelectric properties. We calculated the effect of the substitution on the effective mass of SrTiO3 by analyzing its structural and electrical properties. When V was used as a substitute, the effective mass increased slightly due to a small change in the V/>O bond distance. Moreover, when Nb and Ta were used as substitutes, the effective mass increased owing to an increase in the electronic density of states near the fermi level due to the increased bond length of Nb(or Ta)<img style=
Keywords:Thermoelectric  Seebeck coefficient  Strontium titanate  Mesoporous  V-group elements
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