石墨烯包覆玻璃纤维复合材料的制备及其电学性能研究

以牛血清白蛋白(BSA)改性玻璃纤维表面, 利用静电吸附原理制备氧化石墨包覆的玻璃纤维复合材料, 采用氢碘酸还原氧化石墨得到石墨烯包覆玻璃纤维导电材料。利用X射线衍射(XRD)和傅立叶变换红外光谱仪(FT-IR)等表征样品的物相结构和基团类型, 扫描电镜(SEM)表征石墨烯包覆玻璃纤维的形貌特征。当氧化石墨分散液pH低于6时, 随着pH减小, 包覆效果变得更明显。通过粒径/Zeta电位仪表征氧化石墨和BSA在不同pH下的Zeta电位, 结果表明BSA等电点约为5.3, 氧化石墨的等电点小于3。得到的石墨烯包覆玻璃纤维导电材料的电导率达到4.5 S/m, 制备的导电玻璃纤维具有一定的柔性, 在弯曲后仍能保持原有的导电性能; 导电玻璃纤维在高于100℃热处理后, 由于石墨烯在高温下可以继续还原, 其电导率得到一定的提高, 表明制备的导电玻璃纤维可以在较高温度下使用。

Preparation and Electrical Properties of Graphene Coated Glass Fiber Composites

The graphene coated glass fiber composites were obtained from the electrostatic adsorption of graphene oxide on bovine serum albumin (BSA) modified the glass fibers, and the subsequent reduction of graphene oxide coated glass fibers by hydroiodic acid at low temperature of 40℃. The phase structure and functional groups of graphene oxide were studied by XRD and FT-IR, respectively. SEM images showed that the graphene wrapped effect was improved with pH decreasing, when pH of graphene oxide dispersion was less than 6. Zeta potential of graphene oxide and BSA molecule were tested by Particle size/Zeta potential instrument, which showed that the isoelectric points of graphene oxide and BSA were smaller than 3 and 5.3, respectively. Conductivity of graphene wrapped glass fiber composites reached 4.5 S/m, and conductive glass fibers maintained original conductivity after different levels of bending. Moreover, due to the reduction of graphene, the conductivity increased slightly after the heat-treatment above 100℃. These results prove that the conductive glass fibers can be used at high temperature.