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Hydrogenation of soybean oil by nickel/silica catalysts in a rotating packed disk reactor
Authors:Sun Choia  Young Sung Ghima  Ho Nam Change  J. S. Rhee
Affiliation:(1) Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, P.O. Box 131, Dongdaemun, Seoul, Korea;(2) Department of Biological Science and Engineering, Korea Advanced Institute of Science and Technology, P.O. Box 131, Dongdaemun, Seoul, Korea;(3) Yukong Ltd., Seoul, Korea;(4) Energy Laboratory, Korea Institute of Energy and Resources, P.O. Box 339, Daejeon, Chungnam, Korea
Abstract:
Hydrogenation of soybean oil was carried out by nickel/ silica catalysts in a newly developed rotating packed disk reactor (RPDR). The rotation of a catalyst-filled disk facilitated hydrogen transfer into the liquid phase and mixing in the reactor, resulting in an improved threephase reaction. Performance of RPDR in a batch operation was studied by varying temperature, pressure, nickel concentration in the oil, and disk rotating speed. The overall reaction rate increased with these variables, but the selectivity of linoleic acid was high when the hydrogen transfer controlled the reaction on the catalyst.
Keywords:
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