Densification and phase transformation of Si3N4 in the presence of mechanically activated BaCO3–Al2O3–SiO2 mixture

Densification as well as the →β phase transformation of Si₃N₄ were monitored as a function of activation time of the BaCO₃–Al₂O₃–SiO₂ additive mixture. The composition of the ternary mixture corresponded to celsian (BaAl₂Si₂O₈—BAS). Previously, mechanically activated powder mixtures for various lengths of time were added to Si₃N₄ in the amount of 10–30%. Sintering was performed at 1650–1700°C in nitrogen atmosphere up to 8 h. The changes in densification degree, as well as phase composition, were followed as a function of heating time and the time of mechanical activation of the additive mixture. The results obtained showed that mechanical activation retarded densification in samples heated up to 1700°C. On the other hand, for the constant sintering time, →β transformation of Si₃N₄ was enhanced with increasing activation time, and the amount of additives.