Raman spectroscopy investigation of structural and textural change in C/C composites during braking |
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Authors: | LEI Bao-ling YI Mao-zhong XU Hui-juan RAN Li-ping GE Yi-cheng PENG Ke |
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Affiliation: | (1) State Key Laboratory of Powder Metallurgy, Central South University, Changsha, 410083, China |
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Abstract: | The microstructure and texture of C/C composites with a resin-derived carbon, a rough laminar (RL) pyrocarbon and a smooth
laminar pyrocarbon, before and after braking tests, were investigated by Raman spectroscopy. The full width at half maximum
(FWHM) of the D-band indicates the amount of defects in the in-plane lattice, while the G-to-D band intensity (peak area)
ratios (I
G/I
D) is used to evaluate the degree of graphitization. The results show that the FWHM of D-band of sample with RL pyrocarbon
changes greatly from 36 cm−1 to 168 cm−1 after braking tests, which indicates that a large number of lattice defects are produced on its wear surface. However, the
graphitization degree of resin-derived carbon sample rises significantly, because the I
G/I
D increases from 0.427 to 0.928. Braking tests under normal loading conditions, involving high temperature and high pressure,
produce a lot of lattice defects on the wear surface, and induce the graphitization of the surface. Sample with RL pyrocarbon
having a low hardness is easy to deform, and has the most lattice defects on the wear surface after braking. While raw materials
with resin-derived carbon have the lowest graphitization degree which rises greatly during braking. |
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Keywords: | C/C composites Raman spectroscopy graphitization degree braking |
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