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THERMODYNAMICS OF BAINITIC TRANSFORMATION IN Cu-24 at.-% Al ALLOY
作者姓名:XU  Zuyao
摘    要:Two driving forces △G~((β_1)+α')and △G~(β_1→β_2+α)for the bainitic transformation have been calcu-lated for Cu-24 at.-% Al alloy.Results reveal △G~(β_1→α')>0 within the transformation tem-perature range 600—750 K.Therefore,the bainitic transformation cannot be initiated by theβ_1→α' shearing mechanism.On the other hand,the driving force △G~(β_1→β_2+α)to produce 5% ofthe α becomes negative only when the composition of the α satisfiesx_(Al)~α≤0.204 at 700 K or x_(Al)~α=0.209 at 750 K.So the bainitic transformation can only proceedby β_1→β_2+α diffusional reaction with different diffusion amount at different temperatures.

收稿时间:1992-12-25
修稿时间:1992-12-25

THERMODYNAMICS OF BAINITIC TRANSFORMATION IN Cu-24 at.-% Al ALLOY
XU Zuyao.THERMODYNAMICS OF BAINITIC TRANSFORMATION IN Cu-24 at.-% Al ALLOY[J].Acta Metallurgica Sinica(English Letters),1992,5(6):465-467.
Authors:XU Zuyao ZHOU Xiaowang Shanghai Jiaotong University  China Professor
Abstract:Two driving forces △G~((β_1)+α')and △G~(β_1→β_2+α)for the bainitic transformation have been calcu- lated for Cu-24 at.-% Al alloy.Results reveal △G~(β_1→α')>0 within the transformation tem- perature range 600—750 K.Therefore,the bainitic transformation cannot be initiated by the β_1→α' shearing mechanism.On the other hand,the driving force △G~(β_1→β_2+α)to produce 5% of the α becomes negative only when the composition of the α satisfies x_(Al)~α≤0.204 at 700 K or x_(Al)~α=0.209 at 750 K.So the bainitic transformation can only proceed by β_1→β_2+α diffusional reaction with different diffusion amount at different temperatures.
Keywords:Cu-Al alloy  bainitic transformation  thermodynamics
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