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Meso—四—(4—甲基,3—磺基苯基)卟啉分光光度法测定葡萄糖酸锌含量
引用本文:杨(钅监)锋,黄丽英,张婉春. Meso—四—(4—甲基,3—磺基苯基)卟啉分光光度法测定葡萄糖酸锌含量[J]. 福建分析测试, 2001, 10(1): 1372-1375
作者姓名:杨(钅监)锋  黄丽英  张婉春
作者单位:福建医科大学药学系化学教研室,福州,350001
摘    要:本文研究了在抗坏血酸存在下TTPS_4与Zn(Ⅱ)的显色反应。结果表明:在PH为4.40的NaAc—HAc缓冲体系中,以抗坏血酸和吐温—60为辅助配位剂,在沸水浴中加热8分钟,Zn(Ⅱ)与TTPS_4即形成稳定的高灵敏度配合物,最大吸收波长位于430 nm,ε_(430)=5.5×10~5。Zn(Ⅱ)浓度在0~0.120μg/ml范围内遵守比耳定律。应用此法直接测定补锌口服液葡萄糖酸锌含量,结果满意。

关 键 词:Meso-四-(4-甲基,3-磺基苯基)卟啉  抗坏血酸  分光光度法  葡萄糖酸锌。

Study on the spectrophotometric determination of zinc gluconate with meso-Tetra- (4-methyl-3-sulfonate phenyl porphine (ttps4)
Yang Jian feng,Huang Liying,Zhang Wanchun. Study on the spectrophotometric determination of zinc gluconate with meso-Tetra- (4-methyl-3-sulfonate phenyl porphine (ttps4)[J]. Fujian Anal Ysis & Testing, 2001, 10(1): 1372-1375
Authors:Yang Jian feng  Huang Liying  Zhang Wanchun
Abstract:The spectrophotometric determination of Zinc Gluconate with TTPS_4 has been studied in the presente of Tween-60, HAc-NaAc buffer solutcon (pH4.40) and Vitamin C, the complex of Zinc with TTPS_4 is formed after 8min and has maximum absorbtion at 430nm. Its apparent molar absorptivity was 5.5×10~5L·mol~(-1)·cm~(-1). Beer's law was obeyed in the range of 0~0.120μg·ml~(-1). The method could be used for the determination of Zinc in Zinc Gluconate solution with satisfactory results.
Keywords:Meso-tetra-(4-methyl-3-sulfonate phenyl) porphine (TTPS_4)  Vitamin C  Zinc Gluconate  Spectrophotometric method
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