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有机化纳米SiO2填充改性尼龙6复合材料的研究
引用本文:杜拴丽,李迎春. 有机化纳米SiO2填充改性尼龙6复合材料的研究[J]. 塑料工业, 2007, 35(8): 25-27
作者姓名:杜拴丽  李迎春
作者单位:中北大学化工与环境学院,山西,太原,030051;中北大学化工与环境学院,山西,太原,030051
摘    要:通过酰氯化法制备了有饥化的纳米SiO2,用熔融共混法制备了尼龙6/有机化纳米SiO2复合材料,研究了复合材料的力学性能和结晶形态。研究表明:有机化纳米SiO2的加入能够提高尼龙6的拉伸强度和冲击强度,改性效果明显好于未经表面处理的纳米SiO2;偏光显微镜照片显示,有机化纳米SiO2的加入起到了异相成核的作用,使尼龙6的结晶形态发生了改变,由大的球晶变为细小的晶粒。

关 键 词:尼龙6  有机化纳米SiO2  力学性能  结晶形态
文章编号:1005-5770(2007)08-0025-03
修稿时间:2007-04-23

Study on Property of Nylon 6/Nano-meter Organo-SiO2 Composite
DU Shuan-li,LI Ying-chun. Study on Property of Nylon 6/Nano-meter Organo-SiO2 Composite[J]. China Plastics Industry, 2007, 35(8): 25-27
Authors:DU Shuan-li  LI Ying-chun
Affiliation:Institute of Chemical Industy and Ecology, North University of China, Taiyuan 030051, China
Abstract:Nano-meter organo-SiO2 was prepared by means of acyl-chloridate methods. Nylon 6/nano-meter organo-SiO2 composites with different contents of nano-meter organ-SiO2 were prepared by melt blending, and the mechanical properties and crystallization morphology of the composites were studied. The results showed the addi- tion of the nano-meter organo-SiO2 could improve the impact strength and tensile strength of the nylon 6. The modi- fied effect of the nano-meter organo-SiO2on nylon 6 was better than that by neat nano-SiO2 obviously. The results of PLM micrograph showed the nano-meter organo-SiO2 had a heterogeneous nucleation effect on the crystallization, decreased the crystal size of nylon 6.
Keywords:Nylon6   Organo-SiO2    Mechanical Properties   Crystallization Morphology
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