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Synthesis of non-equilibrium phases in immiscible metals mechanically mixed by high pressure torsion
Authors:Tatsuya Miyazaki  Daisuke Terada  Yoji Miyajima  Challapalli Suryanarayana  Reiko Murao  Yoshihiko Yokoyama  Kazumasa Sugiyama  Minoru Umemoto  Yoshikazu Todaka  Nobuhiro Tsuji
Affiliation:(1) Department of Materials Science and Engineering, Graduate School of Engineering, Kyoto University, Yoshida Honmachi, Sakyo-ku, Kyoto 606-8501, Japan;(2) Department of Materials Science and Engineering, Tokyo Institute of Technology, Nagatsuta-cho, Midori-ku, Yokohama Kanagawa, 226-8503, Japan;(3) Department of Mechanical, Materials and Aerospace Engineering, University of Central Florida, Orlando, FL 32816-2450, USA;(4) Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan;(5) Department of Production Systems Engineering, Toyohashi University of Technology, Hibarigaoka 1-1, Tempaku, Toyohashi Aichi, 441-8580, Japan
Abstract:The structural changes in mechanically mixed metals of immiscible combinations of elements caused by bulk mechanical alloying (MA) through the use of high pressure torsion (HPT) were investigated in Ag–Ni and Nb–Zr systems. There was no alloying between Ag and Ni on atomic scale even after 100 rotations of HPT. On the other hand, the β-Zr phase started to appear after HPT 2 rotations in the Nb–Zr system, even though β-Zr is a high temperature phase. Further, Nb and Zr were completely mixed to form a bcc structured single phase after HPT 100 rotations. The sequence of alloying in the Nb–Zr system during HPT was discussed. These results clearly suggest that non-equilibrium phases can form in the Nb–Zr system by bulk MA by the use of HPT.
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