Lead-free NKN-5LT piezoelectric materials for multilayer ceramic actuator

As a candidate for lead-free piezoelectric materials, Li₂O excess 0.95(Na_0.5K_0.5)NbO₃–0.05LiTaO₃ (NKN-5LT) ceramics were developed by conventional sintering process. Sintering temperature was lowered by adding Li₂O as a sintering aid. Abnormal grain growth in NKN-5LT ceramics was observed with varying Li₂O content. In the 1 mol% Li₂O excess NKN-5LT samples sintered at 1000°C for 4 h in air, electromechanical coupling factor and piezoelectric constant of NKN-5LT ceramics were found to reach the highest values of 0.37 and 250 pC/N, respectively. Lead-free piezoelectric ceramic, Li₂O excess NKN-5LT, multilayer ceramic actuators (MLCA) were fabricated. 10?×?10?×?1 mm³ size MLCAs were fabricated by conventional tape casting method. The displacement of Li₂O excess NKN-5LT MLCA with 3 mm thickness was ~1 μm at 150 V.