FREE RADICALS FORMED IN HYDROTREATED COAL LIQUID AND INFLUENCE OF OXYGEN |
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Authors: | Yoshio Yamada Akimitsu Matsumura Teruo Kondo Koji Ukegawa Etsuro Nakamura |
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Affiliation: | National Research Institute for Pollution and Resources , Yatabe, Ibaraki, 305, Japan |
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Abstract: | ABSTRACT The behavior of radicals formed in hydrotreated coal liquid with heat treatment and the influence of oxygen have been investigated by electron spin resonance (e.s.r.) spectroscopy. A set of e.s.r. spectral lines identified as phenalenyl radical appears from 50°C as the oil is heated in argon atmosphere. The radical concentration is enhanced with temperature, reaches a maximum between 130 and 150°C and then decreases at higher temperatures. The radical is very stable even at 200°C for the sample hydrotreated under mild condition, whereas the radical in the sample treated under severe conditions disappears drastically from 150°C. When oxygen is introduced in the oil, the radical is converted into semiquinone and/or aryloxy radicals and stable molecules. The treatment in the presence of oxygen at higher temperatures is considered to accompany the formation of other aryloxy radicals by the reaction of aromatic hydrocarbons and oxygen. |
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