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剑麻纤维增强胶原基复合材料
引用本文:郑学晶,秦树法,马力强,史令茹,汤克勇.剑麻纤维增强胶原基复合材料[J].复合材料学报,2008,25(3):12-19.
作者姓名:郑学晶  秦树法  马力强  史令茹  汤克勇
作者单位:郑州大学,材料科学与工程学院,郑州,450052
摘    要:用戊二醛作交联剂对皮革下脚料中提取的胶原水解物进行交联改性,采用溶胀度表征了材料的交联程度。探讨了戊二醛用量、胶原蛋白浓度和丙三醇含量对材料溶胀度的影响,并使用红外光谱对交联产物进行了表征。以改性胶原蛋白为基体、剑麻纤维为增强相,制备了剑麻纤维/胶原蛋白复合材料。用扫描电子显微镜对复合材料的形貌进行了表征,探讨了剑麻纤维的表面处理、纤维含量以及长度对复合材料力学性能的影响。结果表明,对剑麻纤维表面进行碱处理可以改善纤维的表面结构,增加纤维与基体的界面粘结,提高复合材料的力学性能。当剑麻纤维质量分数为15 %、纤维长度为 7~8 mm时,复合材料具有较好的力学性能。该复合材料可望在包装垫隔材料方面得以应用。 

关 键 词:胶原蛋白    剑麻纤维    复合材料    溶胀度    力学性能
文章编号:1000-3851(2008)03-0012-08
收稿时间:2007-07-17
修稿时间:2007年7月17日

Sisal f iber reinforced collagen composites
ZHENG Xuejing,QIN Shufa,MA Liqiang,SHI Lingru,TANG Keyong.Sisal f iber reinforced collagen composites[J].Acta Materiae Compositae Sinica,2008,25(3):12-19.
Authors:ZHENG Xuejing  QIN Shufa  MA Liqiang  SHI Lingru  TANG Keyong
Affiliation:(College of Materials Science and Engineering| Zhengzhou University| Zhengzhou 450052| China)
Abstract:The collagen was crosslinked by glutaraldehyde ( GTA) . The influences of the GTA content , collagen concent ration and glycerol content on the swelling ratio of the modified collagen were investigated. Using the modi2fied collagen as the mat rix and sisal fiber as the reinforcement , the sisal fiber/ collagen composite was prepared. The morphologies of the composites were characterized by using scanning elect ron microscopy (SEM) . The influences of the sisal fiber t reatment , fiber content and fiber length on the mechanical properties of the composites were discussed. It is found that the alkali t reatment improves the surface st ructure of the sisal fiber and increases the mechanical properties of the composite. The mechanical properties were improved dramatically when the sisal fiber mass f raction is 15 % and the fiber length is 7~8 mm. The composites can be used as packaging materials.
Keywords:collagen  sisal fiber  composites  swelling ratio  mechanical properties
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